Maxwell's Fourth Equation.
Capacitance. If the terminals of the dry cell are
connected by wires to a pair of parallel plates, the plates become
charged in a small fraction of second and then a potential difference
of 1.5 volts appears between the two plates. This device consisting
of parallel plates separated by air or some insulating material
is a simple form a capacitor. Each of the two plates has an electric
charge Q, but of opposite sign. This charge Q is
directly proportional to the impressed potential difference V.
That is,
Q = CV, (14)
where the constant of proportionality C is called the capacitance
of the capacitor. The symbol for capacitance is C and
solving formula (14) for the capacitance, we find that the capacitance
of a capacitor is the ratio of its charge to the potential difference
across its plates. That is,
C = Q/V. (15)
The unit of capacitance is the farad, abbreviated with
letter f, and is equal to a coulomb per volt. The farad
is so large that, for practical purposes, capacitance is usually
measured in microfarads (μf) or micromicrofarads
(μμf) that is also called a picofarads (pf),
whose values are
1 μf = 10-6, and
1 μμf = 1 pf = 10-12 f.
In general a capacitor is a device that stores electrical
potential energy in the form of an electric field. We can calculate
the electric potential energy U of a charged capacitor
by computing the amount of work W that must be performed
to charge the capacitor to an electric potential V. Using
the definition of electric potential as the instantaneous rate
that work is done per unit of charge, that is,
V = dW/dq, (16)
and, solving equation (16) for dW, the work done
in charging the capacitor from q = 0 to q = Q
is found by integrating the differential equation
dW = Vdq = (q/C)(dq) =
qdq/C.
That is,
U = W0→Q =
∫0QdW =
∫0QVdq =
∫0Qqdq/C =
½Q2/C,
since at any time when the charge q is being transferred,
the potential difference V between the plates is
V = q/C.
Thus the electric potential energy U of a capacitor of
capacitance C whose plates have the charge Q is
U = ½Q2/C, (17)
or, using formula (14), in terms of capacitance and voltage,
U = ½[(CV)2/C] =
½CV2, (18)
or in terms of charge and voltage,
U = ½[(CV)V] = ½QV, (19)
where the capacitor has electric potential energy U because
work was done to charge the capacitor. This potential electric
energy is stored in the electric field between the plates of the
capacitor and the density of this potential electric energy can
be calculated. Energy density u is defined as the
energy per unit volume. For a parallel plate capacitor (with
small plate separation and large plate area), since the capacitance
C = εA/s
and the potential difference across its plates V = Es,
the electric potential energy is
U = ½CV2 =
½(εA/s)(Es)2 =
½εE2(As),
where the factor As is the volume occupied by the electric
field between the plates of the capacitor. Thus the electric
energy density is
u = U/As =
[½εE2(As)]/(As) =
½εE2. (20)
That is, the electric energy density of an electric field is directly
proportionality to the square of the electric field intensity.
While this relation is derived for the specific case of a parallel
plate capacitor, it is a completely general result.
Parallel Capacitance. If two capacitors are connected
in parallel, then their total capacitance is
C = Q/V =
(Q1 + Q2)/V =
Q1/V + Q2/V =
C1 + C2. Thus,
C = C1 + C2. (21)
That is, the total capacitance of a parallel arrangement of capacitance
elements is equal to the sum of the capacitances of each element.
Series Capacitance. If two capacitors are connected
in series, then the total capacitance is
Q/C = V = V1 + V2 =
Q1/C1 +
Q2/C2.
But since Q = Q1 = Q2, then
1/C =
1/C1 +
1/C2. (22)
That is, the reciprocal of the total capacitance of a series arrangement
of the capacitance elements is equal to the sum of the reciprocals
of the capacitance of each element in the series.
Charging a Capacitor. Now consider a circuit consisting of a capacitor with a capacitance C in series with a resistance R connected through a switch to a battery with an EMF of V volts. Assume that the capacitor is initially uncharged (the charge on the two plates are equal) and there is no current flowing in the circuit when the switch is open. When the switch is closed at time t = 0, charges begin to flow, setting up a current in the circuit and the capacitor begins to charge. Since the plates of the capacitor are separated by an insulator of some kind so that no current flows between the plates. As the charge builds up on the plate connected to the positive terminal of the battery, the charge on the other plate of the capacitor connected to the negative terminal of the battery is repelled as the current flows toward the negative terminal of the battery. This continues until the capacitor is fully charged. The value of the maximum charge depends upon the EMF of the battery. Once the maximum charge is reached, the current in circuit is zero.
To analyze quantitatively what happens after the switch is closed,
let us start with the fact that the EMF voltage of the battery
is equal to the sum of potential differences across the capacitor
VC = q/C and across the resistor
VR = IR. That is,
V = VR + VC =
IR + q/C. (23)
Note that the charge and current are variables whose instantaneous
values change as the capacitor charges. At time t = 0,
when the switch closed, the charge on the capacitor is zero, and
the initial value of current I0 is a maximum and is equal
to I0 = V/R. At this time the applied voltage
is entirely across the resistor. Later, when the capacitor is
fully charged to its maximum value Q, the charges cease
to flow (the current is zero), and the applied voltage is entirely
across the capacitor. The charge Q on the capacitor is
then equal CV. To determine an analytical expression for
the time dependence of the charge and current, the equation (23)
must be differentiation with respect to time.
dV/dt = R(dI/dt) +
(1/C)(dq/dt),
since I = dq/dt.
Since the EMF voltage is zero, then
dV/dt = 0. Thus
0 = R(dI/dt) + (1/C)(dq/dt) or
R(dI/dt) = -(1/C)I,
Separating the variables and rearranging the equation, we get
dI/I = (1/RC)dt.
Since R and C are constants, this can be integrated
using the initial conditions that at t = 0,
I = I0. Integrating, we get
ln(I/I0) =
-t/RC. (24)
Solving this equation for I, we get a formula for current as
function of time.
I(t) =
I0e-t/RC =
(V/R)e-t/RC, (25)
where e is the natural logarithmic base and the
I0 = V/R is the initial current.
In order to find the charge on the capacitor as a function of
time, substitute I = dq/dt into equation (25),
I(t) = dq/dt =
(V/R)e-t/RC
or, separating the variables, .
dq =
(V/R)e-t/RCdt
Integrating, using the condition q = 0 at t = 0, we get
q(t) = CV[1 - e-t/RC] =
Q[1 - e-t/RC], (26)
since Q = CV is the maximum charge on the capacitor.
Note that the charge is zero at t = 0 and approaches exponentially
the maximum value of Q at time t . Also the current
has its maximum value I0 = V/R at t
= 0 and decays exponentially to zero as t → ∞.
The quantity RC, which appears in the exponentials of equations (25)
and (26), is called the time constant τ of the circuit.
It represent the time it takes for the current to decrease to
1/e of its initial value; that is, in the time equal to
the time constant τ, the current decays to
I = I0e-1 =
0.37I0,
and the charge on the capacitor will increase to
q = Q[1 - e-1] =
Q[1 - 0.37] = 0.63Q.
The following dimensional analysis shows that
the product RC has the unit of time
[τ] = [RC] = [(V/I) × (Q/V)] =
[Q/I] = [Q/(Q/T)] = [Q].
Discharging a Capacitor. Now consider a circuit
consisting of a capacitor C with an initial charge Q,
a resistor R, and switch, but no source of EMF. When
the switch is open, there is a potential difference of
V = Q/C across the capacitor and zero potential
difference across the resistor since I = 0. When the switch
is closed at t = 0, the capacitor begins to discharge through
the resistor. At some time during the discharge, the current
in the circuit is I and the charge on the capacitor is
q. Now the voltage across the resistor, IR, must
equal the potential difference across the capacitor, q/C.
VR = VC, or
IR = q/C.
However, the current in the circuit must equal the rate of decrease
of charge on the capacitor; that is,
I = -dq/dt.
-R(dq/dt) = (q/C)
or, separating the variables and rearranging the equation, we get
ln(q/Q) = -(t/RC).
Integrating this equation using the fact that q = Q
at t = 0, we get
q(t) = Qe-t/RC. (27)
In order to get the current as a function of time, differentiate
equation (27).
I = dq/dt =
(Q/RC)e-t/RC, (28)
where the initial current I0 = Q/RC.
Both the charge on the capacitor and the current decay are exponential
at a rate characterized by the time constant τ = RC.
Current Density. If the current is distributed
uniformly throughout the cross section area of a wire, then the
current density J is uniform and is given by the total
current I divided by the cross-sectional area A
of the wire. That is,
J = I/A, (29)
where in rationalized MKS system of units the current is measured
in amperes, the cross-sectional area in square meters, and the
current density in amperes per square meter (Am-2).
If the current is not uniformly distributed, equation (29) gives
the average current density. However, it is often of necessary
to consider the current density at a point. This instantaneous
current density is defined as the limit of the ratio of current
I through a small cross-sectional area s to that
area s as s approaches zero. Hence, the current
density at a point is given by
J = lim(ΔI/Δs) =
dI/ds, (30)
where the surface Δs is taken as normal to the current direction.
The current density J is a vector point function
having a magnitude equal to the current density at the point and
its direction is the direction of the current at the point.
Now consider a block of the conducting material. Imagine a small
rectangular cell of length L and cross-sectional area A
enclosing a point P in the interior of the block with the
cross-sectional area A perpendicular to the direction of
the current density J. Applying Ohm's Law to this
cell, we have V = IR, where V is the potential
difference between the ends of the cell and R is the resistance
of the conducting material in the cell. But V = Es = EL
and by equation (29)
I = JA; so that by substitution into Ohm's Law we get
EL = JAR or
J = (L/RA)E = σE, (31)
where σ = (L/RA) is called the conductivity of the
conducting material and is the reciprocal of resistivity ρ; that is,
σ = 1/ρ, where ρ = RA/L.
By making the cell enclosing point P as small as we wish, this relation
can be made to apply at the point P and can be written as a vector
equation.
J = σE. (32)
Equation (32) is Ohm's Law at a point and relates the current
density J at a point to the electric field intensity
E at the point and the conductivity σ of the material.
Here it is assumed that the conducting material is homogeneous
(same material throughout), isotropic (resistance between
opposite faces of a cube independent of the pair chosen), and
linear (resistance independent of current).
Displacement Current. Consider a voltage applied to a resistor and a capacitor in parallel. The nature of the current flow through the resistor is different from that through the capacitor. A constant voltage applied across a resistor produces a continuous flow of current of a constant value. But there will be current through the capacitor only while the voltage is changing, during charging or discharging of the capacitor.
For a voltage V across a resistor of resistance R
and a capacitor of capacitance C in parallel, the current
through the resistor is given by I1 = V/R
and a current through the capacitor given by
I2 = dQ/dt =
C(dV/dt), (33)
where instantaneous charge dQ in the capacitor is given by
dQ = CdV. The current through the resistor is called
conduction current, while the current "through"
the capacitor may be called a displacement current. Although
the current does not flow through the capacitor, the external
effect is as though it did, since as much current flows out of
one plate as flows into the opposite one. Fringing of the electric
field can be neglected. Now inside each element, the electric
field E equals the voltage V across the element
divided by its length L. That is,
E = V/L.
From equation (29) the current density J1 inside
the resistor equals to I1 divided by the cross-sectional
area A; it is also equal to the product of the electric
field E and the conductivity σ of the medium inside the
resistor element; That is,
J1 = I1/A =
(V/R)(1/A) = (V/L)(L/RA) =
Eσ. (34)
In RMKS units, the dimensional analysis of equation (34) is
ampers/meter2 = (volts/meter)(meter/ohms·meter2).
The capacitance of a parallel plate capacitor is
C = εA/s,
where A is the area of one of the plates and s is
the spacing between them. Substituting this value for C
into equation (33), we get
I2 = dQ/dt =
C(dV/dt) =
(εA/s)(dV/dt) =
(εA/s)(sdE/dt) =
εA(dE/dt), (35)
since V = Es. Dividing equation (35) by the cross-sectional
area A, we get the relation between the current density
J2
inside the capacitor that is equal to the permittivity of the
nonconducting medium filling the space between the plates of the
capacitor multiplied times the rate of change of the electric
field intensity. That is,
I2/A = J2 =
ε(dE/dt). (36)
In RMKS units, the dimensional analysis of equation (36) is
amperes/meter2 = (farad/meter)[(volt/meter)/second] =
[(coulomb/volt)/meter][(volt/meter)/second] =
(coulomb/second)(1/meter2).
Since electric flux density D = εE, then equation
(36) becomes
J2 = dD/dt. (37)
In our circuit above J1 is called the conduction current
density Jcond and J2 is called the
displacement current density Jdisp. Now the total
current density J in this parallel circuit is equal to the sum of
Jcond and Jdisp. Now, since current
density J, the electric flux density D, and the
electric field intensity E are actually space vectors, which all
have the same direction in isotropic media, then equations (34)
and (37) may be expressed more generally as vector equations.
Jcond = σE, (38)
Jdisp = dD/dt =
εdE/dt, (39)
and
J =
Jcond +
Jdisp. (40)
The concept of displacement current, or displacement current density,
was introduced by James Clerk Maxwell to account for the production
of magnetic fields in empty space. There the conduction current
is zero, and magnetic fields are due entirely to displacement currents.
Ampere's Law and Maxwell's Equation. According
to Ampere's Law, the line integral of magnetic field intensity
H around a closed contour or path is equal to the
current I enclosed, that is,
∫λ(H · dλ =
I.
Where both conduction and displacement currents are present, the
current I is the total current. If we let S
be any surface whose periphery is the path of integration λ, then
in terms of the current density J (the current per
unit area), this total current through S is
I =
∫∫SJ · dS.
Hence, we get
∫λ(H · dλ =
∫∫SJ ·
dS. (41)
But since by equation (40) J =
Jcond + Jdisp,
then equation (41) may written
∫λ(H · dλ =
∫∫S(Jcond +
Jdisp) · dS. (42)
Using equation (39), equation (42) is usually written
∫λ(H · dλ =
∫∫S[J + (dD/dt)]
· dS, (43)
where J without the subscript refers only to the
conduction current density. This equation is the complete expression
of the integral form of Maxwell's equation derived from
Ampere's Law. By the application of Stokes' theorem to equation
(43), we get the differential form of Maxwell's equation
derived from Ampere's Law, sometimes also called Maxwell's
postulate:
∇ × H = J +
dD/dt. (44)
This equation is consistent with the equation of continuity.
Equation of Continuity. The equation of continuity
follows from the principle of conservation of charge which states
simply that electric charge cannot be created or destroyed, that
is, electric charge can be produced only in pairs of equally strong
positive and negative charges. The experimental proof, due to
Franklin, is a simple experiment: Wrap an uncharged silk cloth
around an uncharged glass rod. Rub the rod and separate the cloth
from the rod; each individually exerts a strong electric forcs
of attraction or repulsion on some third object, such as the charged
leaf of tinfoil in an electroscope. Now if the charged cloth
is wrap again around the charged rod, then electric forces exerted
on some third object disappear. The conclusion from this experiment
is that electric charge is not created or destroyed but that the
rubbing separated equal amounts of charge but with opposite signs
on the rod (positive) and the cloth (negative), and when they
are brought together again, the equal but opposite charges cancel
each other. No net charge (execss of + and -) is created by the
friction of the rubbing. This is the principle of the conservation
of electric charge and the equation of continuity follows from
this principle, when we consider any region bounded by a closed
surface. The electric current flowing through the closed surface is
I = ∫∫SJ · dS
and this outward flow of positive charge must be balanced by a
decrease of positive charge (or perhaps an increase of negative
charge) within the closed surface. If the charge inside the closed
surface is designated by Q, then the rate of decrease is
-dQ/dt and the principle of the conservation of charge
requires that
I = ∫∫SJ · dS
= -dQ/dt. (45)
Why the negative sign? The answer is that the presence or absence
of a negative sign depends upon what current and charge is being
considered. In circuit theory the current flow into one
terminal of a capacitor is associated with the time rate of increase
of charge on that plate. The current in the above equation (45)
is an outward-flowing current and the time-rate of change
of charge through the surface is negative, a decrease of charge
within the enclosing surface.
Equation (45) is the integral form of the equation of continuity,
and the differential, or point, form may be obtained by changing
the surface integral into a volume integral by the divergence theorm,
∫∫SJ · dS =
∫∫∫(∇ · J)dV,
and by representing the enclosed charge Q by the volume
integral of the charge density ρ, that is,
Q = ∫∫∫ρdV.
Hence, equation (45) becomes
∫∫∫(∇ · J)dV =
-d/dt∫∫∫ρdV.
If the surface is kept constant, the derivative becomes a partial
derivative within the integral, that is,
∫∫∫(∇ · J)dV =
∫∫∫(-dρ/dt)dV.
Since both volume integrals are taken throughout the same arbitrary
volume, then the integrands may be equated, and we get the differential
or point form of the equation of continuity,
∇ · J =
-(∂ρ/∂t). (46)
Maxwell's Postulate. Maxwell used Faraday's experimental
law to obtain one of his four equations of electromagnetic fields
in differential from:
∇ × E =
-(∂B/∂t). (47)
This equation states that a time-changing magnetic field produces
an electric field. According to the definition of curl, the electric
field has the special property of circulation; its line integral
about a closed path is not zero. To Maxwell this equation suggested
that a time-changing electric field will produce a magnetic field.
Taking his start from the point form of Ampere's Circuital Law,
∇ × H = J, (48)
which applies to steady magnetic field, Maxwell showed its inadequacy
for time-varying electric fields by taking the divergence of each
side of the equation:
∇ · ∇ × H =
0 = ∇ · J.
Since the divergence of the curl is identically zero,
∇ · J is also zero. However, according
to the equation of continuity, equation (46),
∇ · J is not zero and equation (48),
Ampere's Circuital Law, cannot be true for time-varying electric
fields. In order to remove this unrealistic limitation, equation
(48) must be amended in order for it to apply to time-varying
electric fields. This can be done in the following way; let us
add to the right side of equation (48) an unknown term G:
∇ × H = J + G.
Again, taking the divergence of both sides of this equation, we get
∇ · ∇ × H = 0 =
∇ · J +
∇ · G,
or,
∇ · J =
-∇ · G.
But since by the equation of continuity, equation (46),
∇ · J =
-(∂ρ/∂t), (46)
then
∇ · G = ∂ρ/∂t.
Using Maxwell's first equation derived from Coulomb's Law,
∇ · D = ρ and substituting
∇ · D for ρ, we get
∇ · G =
∂(∇ · D)/∂t =
∇ · ∂D/∂t.
Hence, we get the simplest solution for G:
G = ∂D/∂t,
and Ampere's circuital law in point form becomes
∇ × H =
J + ∂D/∂t, (44)
which is called Maxwell's Postulate and is derived from Ampere's
circuital law. This equation is consistent with the equation of
continuity, Coulomb's law, and Ampere's law. [Equation (44) reduces to
equation (48) for a steady state]. In general, then, for a
nonsteady state, equation (44) takes the place of equation (48),
and the equation
∇ × E = 0
takes the place of equation (47).
Maxwell's Postulate is not the only possible way around the inconsistency
of equation (48) with the equation of continuity, equation (46).
For example, let
J + ∂D/∂t =
∇ ×
(B + ∂G/∂t)/μ0
with G as an arbitrary function, would work mathematically.
But, Maxwell would not have been able to derive his theory of electromagnetic
waves. Only with his postulate was Maxwell able to derive his theory.
The exeperimental observation of such waves, with the properties predicted,
may be consider the experimental basis for Maxwell's postulate. And also it
can be shown that this postulate has a reasonable physical interpretation.
The Physical Interpretation of Maxwell's Postulate. Maxwell
originally tried to explain his postulate on mechanical basis, but it was
puzzling. An explanation can be given from another point of view.
Let us start with equation (44) and form the surface integral of
∇ × H over the surface S
whose periphery is λ. We get then
∫∫S(∇ × H)
· dS =
∫∫S(J + ∂D/∂t)
· dS.
Applying Stokes' Theorem to the left side of this equation, we get
∫λH · dλ =
∫∫S(J + ∂D/∂t)
· dS. (49)
But just as
∫λE · dλ
was called the electromotive force (emf) around the path λ, the left
side of equation (49) may be defined as the magnetimotive force (mmf)
around a path λ by the following formula:
mmf = ∫λH ·
dλ. (50)
Substituting this into equation (49), we get
mmf =
∫∫S(J + ∂D/∂t)
· dS. (51)
Equations (49) and (51) show us that there are two ways of producing a
magnetic field intensity:
(a) by means of the ordinary current density J,
as was observed by Oersted and postulated by Ampere,
(b) by means of a changing electric displacement, as postulated by Maxwell.
Since D ∝ E for air or a vacuum, then
a changing electric field produces a magnetic field. This is the converse
of Faraday's discovery that a changing magnetic field produces an electric
field.
Consider the case where J = 0 everywhere, equation (49)
becomes
∫λH · dλ =
∫∫S(∂D/∂t)
· dS, (J = 0) (52)
which is an equivalent statement of Maxwell's postulate expressed soley in
terms Maxwell's new contribution, the ∂D/∂t
term.
Direct observation of a magnetic field produced by a changing electric field is difficult. We cannot look for an induced "magnetic current" because there are neither free magnetic poles nor conductors for magnetic currents. Also, a constant value of ∂D/∂t cannot be maintained long enough to measure the resulting magnetic field, as can be done for a constant electric current producing a magnetic field. Maxwell's Postulate is not as suseptible to direct experimental verification as is Faraday's Law. This is possibly the reason that it was the last fundamental law of classical electromagnetism to be discovered.
If Maxwell's postulate is the converse of Faraday's Law, then why is there
not a converse to Ampere's Law? Or, putting the question differently,
why does the equation (51) for mmf have two terms, while the corresponding
equation for emf,
emf = -∫∫S(∂B/∂t)
· dS, (53)
has only one term? The answer is that the term missing in equation (53)
would involve a current density of "magnetic current" or a flow of magnetic
poles of one sign. And as has been pointed out previously, isolated or
monopoles of one sign and that "magnetic currents" due to them are not
found in our physical world. Thus there is no term analogous to
J in equation (51) and the converse of Ampere's law does not
exist. The fundamental role of electric charges leads to a certain lack
of symmetry in our equations of electromagnetism.